[(Z)-N-(2-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I)
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چکیده
The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], features a linear S,P-donor set with a small deviation from the ideal linear geometry due to the proximity of the meth-oxy O atom to Au [Au⋯O = 2.986 (4) Å].
منابع مشابه
[(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I)
The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S-Au-P = 175.86 (3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thio-carbamato anion [Au⋯O = 2.967 (3) Å].
متن کامل[(Z)-N-(2-Chlorophenyl)-O-methylthiocarbamato-κS](triphenylphosphine-κP)gold(I)
In the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], the Au(I) atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09 (5)°]. The proximity of the meth-oxy O atom to Au may be responsible for the deviation from linearity [Au⋯O = 2.959 (4) Å].
متن کامل[(Z)-N-(4-Chlorophenyl)-O-methylthiocarbamato-κS](triphenylphosphine-κP)gold(I)
The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S-Au-P = 175.14 (5)°] due to the close approach of the O atom to the Au atom [Au⋯O = 2.882 (3) Å]. Loosely associated dimers are formed in the crystal structure through C-H⋯O inter-actions.
متن کامل[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-κS](triphenylphosphine-κP)gold(I)
The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S,P-donor set [S-Au-P angle = 174.61 (4)°], with the distortion related to a short intra-molecular Au⋯O contact [2.988 (3) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis by C-H⋯π inter-actions.
متن کامل[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-κS](triphenylphosphine-κP)gold(I) dichloromethane hemisolvate
The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01 (4)°]; a close intra-molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H⋯N, C-H⋯S and C-H⋯π inter-action...
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